TABLE 3.
Lifetime Data for Ru-Labeled Silica Bead (1 × 102 μM) and Its Silver Shell.
| samples | τi (ns) | αi | 〈τ〉 (ns) | χR2 |
|---|---|---|---|---|
| 1 × 102 μM Ru(bpy)32+ in bare bead | 49.2 568.4 |
0.647 0.353 |
497.3 | 1.2 |
| 10 nm silver shell | 41.1 230.9 |
0.762 0.238 |
161.9 | 1.4 |
| 20 nm silver shell | 34.1 200.8 |
0.772 0.228 |
139.9 | 1.4 |
| 30 nm silver shell | 33.0 209.7 |
0.800 0.200 |
141.4 | 0.9 |
| 40 nm silver shell | 33.3 200.02 |
0.787 0.213 |
136.7 | 1.5 |
| 50 nm silver shell | 32.6 206.9 |
0.799 0.201 |
139.8 | 1.3 |