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Thermodynamic parameters for inversion of 2
| Entry | Description | ΔH‡ (kcal/mol) | ΔS‡ (cal/mol·K) |
|---|---|---|---|
| 1 | Enantiomerization of 2 with 1 equiv. TMEDA | 20.0 ± 1.7 | 12.0 ± 7.1 |
| 2 | DTR of 2 with 1 equiv. 4 | 17.0 ± 0.9 | −14.5 ± 3.2 |
| 3 | DTR of 2 with 4 and 2 equiv. TMEDA | 5.2 ± 0.8 | −53.2 ± 2.9 |
