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. Author manuscript; available in PMC: 2010 Apr 22.
Published in final edited form as: J Am Chem Soc. 2009 Apr 22;131(15):5388–5389. doi: 10.1021/ja901658c

Table 1.

REMP of 1 to give cyclic dendeonized polymer P1a.graphic file with name nihms-108636-t0001.jpg

Entry Catalyst [1]0(M) [1]0/[C]0 Mw (MDa)b DP/1000 PDIb
1 SC-5 0.05 50 5.26 5.84 1.29
2 SC-5 0.10 50 4.06 4.51 1.25
3c SC-5 0.10 100 4.47 4.97 1.51
4d SC-5 0.10 200 5.33 5.92 1.49
5 SC-5 0.20 50 3.90 4.33 1.33
6 SC-5 0.33 50 1.97 2.19 1.17
7 UC-6 0.10 250 3.79 4.21 1.18
a

Unless noted otherwise, reactions were conducted under dry N2 and monitored via 1H NMR spectroscopy until conversions were >90%. [1]0 = initial concentration of 1; [C]0 = initial catalyst concentration

b

Molecular weight data obtained via GPC with multiangle laser light scattering.

c

Maximum conversion = 60%.

d

Maximum conversion = 39%