Table 5.
Values of paH of equimolal (DIPSO + NaDIPSO) buffer solutions from 5 to 55°C, computed using Eqs. (4–6)a
| t(°C) | 0.02 m DIPSO + 0.02 m NaDIPSO I = 0.02 m |
0.04 m DIPSO + 0.04 m NaDIPSO I = 0.04 m |
0.06 m DIPSO + 0.06 m NaDIPSO I = 0.06 m |
0.08 m DIPSO + 0.08 m NaDIPSO I = 0.08 m |
|---|---|---|---|---|
| 5 | 7.755 | 7.843 | 7.854 | 7.855 |
| 10 | 7.654 | 7.740 | 7.752 | 7.753 |
| 15 | 7.559 | 7.642 | 7.651 | 7.655 |
| 20 | 7.464 | 7.544 | 7.555 | 7.557 |
| 25 | 7.374 | 7.454 | 7.465 | 7.467 |
| 30 | 7.286 | 7.362 | 7.367 | 7.374 |
| 35 | 7.201 | 7.275 | 7.282 | 7.288 |
| 37 | 7.170 | 7.240 | 7.248 | 7.250 |
| 40 | 7.119 | 7.188 | 7.193 | 7.197 |
| 45 | 7.043 | 7.106 | 7.113 | 7.115 |
| 50 | 6.962 | 7.023 | 7.033 | 7.034 |
| 55 | 6.886 | 6.945 | 6.956 | 6.957 |
Units of m, mol·kg−1