Table 1.
A Summary of Crystal Data and Refinement Results.
| Formula | Space group | a, b (Å) | c (Å) | R(F) | wR2 | Flack parameter | |
|---|---|---|---|---|---|---|---|
| ATF-1P* | (Me2NH2)[In(thb)2]˙x(DMF) | P4122 | 13.565(5) | 15.503(13) | 0.0488 | 0.1145 | −0.004(61) |
| ATF-1M* | (Me2NH2)[In(thb)2]˙x(DMF) | P4322 | 13.5590(1) | 15.6782(2) | 0.0392 | 0.1457 | 0.014(64) |
| ATF-1 | (Me2NH2)[In(thb)2]˙x(DMF) | P4122 | 13.5770(4) | 15.5394(9) | 0.0378 | 0.0992 | 0.50(5) |
| ATF-2P* | (Et2NH2)[In(thb)2] ˙x(DEF) | P4122 | 13.5100(1) | 16.0684(3) | 0.0526 | 0.1788 | 0.035(86) |
| ATF-2 | (Et2NH2)[In(thb)2] ˙x(DEF) | P4322 | 13.5065(2) | 15.9076(4) | 0.0602 | 0.1916 | 0.55(10) |
H2thb = thiophene-2,5-dicarboxylic acid
superscript “*” indicates these materials were synthesized by using chiral catalysis.