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. Author manuscript; available in PMC: 2010 Nov 5.
Published in final edited form as: J Phys Chem B. 2009 Nov 5;113(44):14545–14548. doi: 10.1021/jp907808t

Figure 2.

Figure 2

The free energy as a function of the collective solvent coordinate generated for the PCET model using standard Marcus theory for (a) ΔG0 = 10 kcal/mol, corresponding to the normal Marcus region with –ΔG0 < λ, and (b) ΔG0 = –30 kcal/mol, corresponding to the inverted Marcus region with –ΔG0 > λ.