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Calculated structures for 5, TS53 (L= P(tBu)2(o-biPh) and metal-free), and TS52 (L=P(OPh)3). Selected bond lengths for TS53 and TS52 with L= P(tBu)2(o-biPh) and L=P(OPh)3 shown in red and blue, respectively. Selected bond lengths for 5 and TS53 for metal-free structures shown in black.