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ORTEP diagram view of the cationic portions of [(LMIm)CuII(CH3CN)]2+ (1c; τ = 0.861, top; 30% probability ellipsoids) and [(LEIm)CuII(CH3CN)(−OClO3)]+ (2c·OClO3; bottom; 30% probability ellipsoids). The hydrogen atoms and non-coordinating perchlorate anions are omitted for clarity.