Table 2.
Selected bond distances and angles for 1c and 2c·OClO3
| [(LMIm)CuII(CH3CN)]2+ (1c) | [(LEIm)CuII(CH3CN)(−OClO3)]+ (2c·OClO3) |
||
|---|---|---|---|
| Cu-N | Bond distance (Å) | Cu-N | Bond distance (Å) |
| Cu(1)-N(1) | 2.037(3) | Cu(1)-N(1) | 2.005(3) |
| Cu(1)-N(2) | 2.035(3) | Cu(1)-N(2) | 2.090 (3) |
| Cu(1)-N(3) | 2.039(3) | Cu(1)-N(3) | 2.183(3) |
| Cu(1)-N(4) | 2.064(4) | Cu(1)-N(4) | 1.972(3) |
| Cu(1)-N(6) | 1.969(3) | Cu(1)-N(6) | 2.014(3) |
| Cu(1)-O(97) | 2.770(9) | ||
| N-Cu-N | Bond angle (°) | N-Cu-N | Bond angle (°) |
|---|---|---|---|
| N(6)-Cu(1)-N(2) | 96.19(13) | N(4)-Cu(1)-N(1) | 161.92(11) |
| N(6)-Cu(1)-N(1) | 177.60(16) | N(4)-Cu(1)-N(6) | 91.52(10) |
| N(2)-Cu(1)-N(1) | 82.16(12) | N(1)-Cu(1)-N(6) | 93.51(11) |
| N(6)-Cu(1)-N(3) | 96.69(13) | N(4)-Cu(1)-N(2) | 94.98(11) |
| N(2)-Cu(1)-N(3) | 125.94(13) | N(1)-Cu(1)-N(2) | 80.63(10) |
| N(1)-Cu(1)-N(3) | 82.93(13) | N(6)-Cu(1)-N(2) | 173.39(10) |
| N(6)-Cu(1)-N(4) | 99.87(14) | N(4)-Cu(1)-N(3) | 97.07(10) |
| N(2)-Cu(1)-N(4) | 116.08(13) | N(1)-Cu(1)-N(3) | 99.57(10) |
| N(1)-Cu(1)-N(4) | 82.44(13) | N(6)-Cu(1)-N(3) | 96.70(10) |
| N(3)-Cu(1)-N(4) | 112.92(14) | N(2)-Cu(1)-N(3) | 81.38(10) |