. Author manuscript; available in PMC: 2010 Dec 7.

Published in final edited form as: Inorg Chem. 2009 Dec 7;48(23):11038–11047. doi: 10.1021/ic901391y

Table 2.

Product Yields for the Reaction of Tq Solutions with Hydrocarbons at −45°C in PrCN.

substrate	atmosphere	product	Yield (equiv./Tq)	A/K ratio
cyclohexene	Ar	2-cyclohexen-1-ol	1.0 ± 0.2	2.5 ± 0.7
		2-cyclohexen-1-one	0.4 ± 0.1
		cyclohexene oxide	trace
cyclohexene	Air	2-cyclohexen-1-ol	1.3 ± 0.3	0.4 ± 0.1
		2-cyclohexen-1-one	3.6 ± 0.1
		cyclohexene oxide	0.0
adamantane^a	Ar	1-adamantanol	0.56	2.8
		2-adamantanone	0.20
styrene	Ar	styrene oxide	0.33 ± 0.04	N/A
		benzaldehyde	0.2 ± 0.1
cis-stilbene	Ar	cis-stilbene oxide	0.09 ± 0.02	N/A
		trans-stilbene oxide	0.05 ± 0.01

Adamantane results were originally reported in reference ¹⁶.