Table 1.

Results of fitting spectra generated by the rigorous theory to eq 1. (a) ¹⁴N nitroxides.

Dispersion and line shifts.
$\frac{4}{3\sqrt{3}}\frac{{\omega }_e}{\gamma A_0}$ a	$\left(\frac{V_{\text{disp}}^{ex}(\pm )}{V_{pp}(\pm )}\right)$ b	$A_{\text{abs}}/A_0$ b	$A_{\text{obs}}/A_0$ c
0.0000	0.0000	1.0000	1.0000
0.037890	0.037986	0.99960	0.99960
0.075781	0.076254	0.99838	0.99838
0.11367	0.11508	0.99636	0.99637
0.15156	0.15477	0.99352	0.99354
0.18945	0.19575	0.98985	0.98991
0.22734	0.23829	0.98536	0.98546
0.26523	0.28292	0.98002	0.98021
0.30312	0.32996	0.97382	0.97416
0.34101	0.38077	0.96676	0.96729
0.37890	0.43530	0.95881	0.95962
0.41679	0.49497	0.94995	0.95114
0.45468	0.56178	0.94018	0.94186
0.49257	0.63783	0.92946	0.93176
0.53046	0.72426	0.91779	0.92086
0.56835	0.82784	0.90515	0.90915
0.60624	0.95396	0.89153	0.89663
0.64413	1.1147	0.87693	0.88331
0.68202	1.3227	0.86137	0.86917
0.71992	1.6183	0.84490	0.85423
0.75781	2.0847	0.82759	0.83849
0.79570	2.9274	0.80958	0.82193
0.83359	4.9254	0.79107	0.80457
Broadening and intensities.
$\frac{4}{3\sqrt{3}}\frac{{\omega }_e}{\gamma A_0}$ a	$B_e(0)/A_0$ b	$B_e(\pm )/A_0$ b	< Be > / A0	Be(±) / Be (0)	I(±)b	I (0)b	I(±) / I(0)0
0.0000	0.0000	0.0000	0.0000	1.0000	0.33334	0.33334	1.0000
0.037890	0.037880	0.037896	0.037891	1.0004	0.33307	0.33388	0.99757
0.075781	0.075699	0.075822	0.075781	1.0016	0.33225	0.33550	0.99031
0.11367	0.11339	0.11381	0.11367	1.0037	0.33088	0.33824	0.97823
0.15156	0.15090	0.15189	0.15156	1.0066	0.32893	0.34214	0.96138
0.18945	0.18815	0.19010	0.18945	1.0104	0.32636	0.34726	0.93981
0.22734	0.22507	0.22848	0.22734	1.0151	0.32314	0.35370	0.91359
0.26523	0.26159	0.26706	0.26524	1.0209	0.31920	0.36156	0.88283
0.30312	0.29762	0.30588	0.30313	1.0278	0.31447	0.37099	0.84765
0.34101	0.33306	0.34500	0.34102	1.0359	0.30887	0.38217	0.80820
0.37890	0.36781	0.38446	0.37891	1.0453	0.30227	0.39532	0.76464
0.41679	0.40175	0.42433	0.41681	1.0562	0.29456	0.41070	0.71720
0.45468	0.43475	0.46468	0.45470	1.0688	0.28555	0.42866	0.66614
0.49257	0.46664	0.50558	0.49260	1.0834	0.27505	0.44960	0.61177
0.53046	0.49725	0.54712	0.53049	1.1003	0.26280	0.47399	0.55445
0.56835	0.52636	0.58941	0.56839	1.1198	0.24853	0.50243	0.49465
0.60624	0.55372	0.63258	0.60630	1.1424	0.23187	0.53561	0.43291
0.64413	0.57904	0.67678	0.64420	1.1688	0.21242	0.57432	0.36986
0.68202	0.60199	0.72217	0.68211	1.1996	0.18974	0.61945	0.30630
0.71992	0.62216	0.76895	0.72002	1.2359	0.16338	0.67190	0.24316
0.75781	0.63913	0.81735	0.75794	1.2788	0.13296	0.73240	0.18154
0.79570	0.65242	0.86759	0.79587	1.3298	0.098316	0.80132	0.12269
0.83359	0.66157	0.91992	0.83380	1.3905	0.059713	0.87812	0.068001

^aInput values. Compare with column 7.

^bFitting simulated spectra to eq 1.

^cComputed from the perturbation values $A_{\text{abs}}/A_0=1-\frac{9}{32}{\left(\frac{B_e}{A_0}\right)}^2.$