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. Author manuscript; available in PMC: 2010 Jun 15.
Published in final edited form as: Inorg Chem. 2009 Jun 15;48(12):5106–5116. doi: 10.1021/ic802440h

Table 2.

E1/2 values for reduction of complexes LtBu,iPr2FeY in Et2O/NBu4BArF and LtBu,iPr2FeY(NCMe) in MeCN/NBu4PF6. Potentials are given in volts relative to the ferrocenium/ferrocene couple at 0 V. 31

Y Et2O MeCN
Cl −2.46(1) −2.32(2)
OPh −2.56(3) −2.27(6)
SPh −2.41(2) −2.30(6)
SPhCF3 −2.40(2) −2.33(1)