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Important bond distances and angles for the four-coordinate Fe(II) complexes. L represents the fourth donor atom (C, N, or O).
| Bond/Angle | CNtBu | MeIm | DMF |
|---|---|---|---|
| Fe-N (Å) | 2.000(2), 2.013(2) | 2.021(2), 2.0262(19) | 2.0181(11), 2.0212(11) |
| Fe-S (Å) | 2.2776(15) | 2.2955(11) | 2.2877(4) |
| Fe-L (Å) | 2.089(2) | 2.094(2) | 2.0832(10) |
| N-Fe-N (°) | 96.19(5) | 96.85(8) | 95.44(4) |
| S-Fe-L (°) | 118.04(7) | 125.58(6) | 110.31(3) |
| Fe-S-L (°) | 104.36(6) | 107.05(8) | 112.94(5) |
