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Calculated solid and cone angles of ligands used in this study.
| Ligand | Solid Ang (Ω) | Cone Ang (θ) | Keq(Cl) |
|---|---|---|---|
| PPh3 | 3.32(6) | 124(1) | 0.70 |
| THF | 1.81(6) | 89(2) | 0.80 |
| MeCN | 1.60(0) | 83.69(3) | 9.80 |
| DMF | 1.63(4) | 85(1) | 390 |
| 2-Picoline | 2.36(3) | 102.8(6) | 660 |
| Pyridine | 1.90(2) | 91.6(5) | 41000 |
| CNtBu | 1.65(1) | 85.0(3) | 90000 |
