Table 1.
Spiked amount (ng/mL) |
Intra-day |
Inter-day |
Extract |
||||
RSD | Ac | RSD | Ac | Recovery | RSD | ||
Rhein | 39.1 | 3.76 | 104.60 | 3.53 | 107.94 | 104.60 | 3.76 |
156 | 5.55 | 100.32 | 5.52 | 106.87 | 100.32 | 5.55 | |
625 | 5.31 | 101.07 | 5.56 | 105.36 | 101.07 | 5.31 | |
3750 | 4.24 | 101.24 | 6.23 | 98.37 | 101.24 | 4.24 | |
Chrysophanol | 6.1 | 2.37 | 99.4 | 4.46 | 98.67 | 99.39 | 2.36 |
24.4 | 4.38 | 104.17 | 4.88 | 101.14 | 104.17 | 4.37 | |
97.7 | 1.64 | 96.66 | 3.33 | 98.09 | 96.66 | 1.64 | |
586 | 3.78 | 103.98 | 4.44 | 101.13 | 103.98 | 3.78 | |
Rheochrysidin | 39.1 | 5.69 | 97.70 | 5.72 | 100.78 | 97.69 | 5.68 |
156 | 3.33 | 99.89 | 4.13 | 101.14 | 99.89 | 3.33 | |
625 | 3.22 | 105.92 | 3.73 | 104.37 | 105.92 | 3.22 | |
3750 | 4.75 | 103.07 | 4.84 | 103.49 | 103.07 | 4.75 | |
Magnolol | 6.1 | 5.51 | 102.13 | 5.07 | 106.33 | 102.13 | 5.51 |
24.4 | 2.39 | 104.78 | 5.79 | 99.86 | 104.78 | 2.39 | |
97.7 | 5.51 | 107.81 | 4.92 | 106.23 | 102.47 | 5.51 | |
586 | 3.77 | 105.97 | 5.33 | 105.29 | 105.97 | 3.77 | |
Hesperidin | 6.1 | 4.12 | 95.96 | 4.82 | 98.49 | 95.96 | 4.12 |
24.4 | 5.83 | 99.52 | 5.10 | 100.29 | 99.52 | 5.83 | |
97.7 | 4.21 | 100.14 | 3.95 | 99.72 | 100.16 | 4.21 | |
586 | 2.77 | 97.13 | 4.91 | 98.52 | 97.13 | 2.76 | |
Naringin | 6.1 | 2.66 | 95.66 | 4.26 | 99.29 | 95.67 | 2.657 |
24.4 | 2.82 | 102.46 | 3.95 | 103.37 | 102.45 | 2.82 | |
97.7 | 3.81 | 100.78 | 3.96 | 100.66 | 100.78 | 3.81 | |
586 | 5.24 | 98.27 | 5.59 | 99.32 | 98.27 | 5.24 |
DCQD: Da-Cheng-Qi Decoction; QC: Quality control.