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. Author manuscript; available in PMC: 2010 Nov 4.
Published in final edited form as: J Am Chem Soc. 2009 Nov 4;131(43):15717–15728. doi: 10.1021/ja905065j

Table 9.

Selected bond lengths of rhodium(I)(cod)chloride/phosphoramidite complexes.

graphic file with name nihms152020t52.jpg
Trans to P Trans to Cl
Ligand Rh–P Rh–Cl Rh–C=C* C=C Rh-C=C* C=C
T9 2.2703(4) 2.3654(4) 2.132 1.409(2) 1.994 1.413(3)
T8 2.2688(6) 2.3765(6) 2.131 1.377(4) 1.992 1.395(4)
T1 2.2648(6) 2.3777(6) 2.140 1.376(4) 1.997 1.417(3)
T2 2.2547(3) 2.3842(3) 2.152 1.3781(18) 1.995 1.4131(16)
A1 2.2451(4) 2.3485(4) 2.162 1.369(3) 2.013 1.409(2)
B4 2.2388(9) 2.3455(8) 2.151 1.365(5) 2.003 1.396(5)
*

Bond length from Rh to centroid of alkene