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. Author manuscript; available in PMC: 2010 Nov 24.
Published in final edited form as: Chem Phys Lett. 2009 Nov 24;483(1-3):1–9. doi: 10.1016/j.cplett.2009.10.051

Figure 8.

Figure 8

Transient kinetics of ReI(CO)3(dmp)(His124)|(Trp122)|AzCuI. (A) Time-resolved luminescence (grey: λobs > 450 nm; λex = 355 nm, 10 ps pulsewidth; pH 7.2), instrument response function (grey), and fit to a three-exponential kinetics model [black: τ1 = 35 ps (growth); τ2 = 363 ps (decay); τ3 = 25 ns (decay)]. (B) Visible transient absorption [λobs = 632.8, 500 nm; λex = 355 nm, 1.5 mJ, 8 ns pulsewidth; pH 7.2]. Black lines are fits to a biexponential kinetics model [τ1 = 25 ns (growth); τ2 = 3.1 ms (decay)].