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. Author manuscript; available in PMC: 2010 Jan 4.
Published in final edited form as: Inorg Chem. 2009 Nov 16;48(22):10708–10719. doi: 10.1021/ic901711c

Chart 1.

Chart 1

Active site structure of reduced soluble methane monooxygenase hydroxylase (sMMOHred, left) and a proposed synthetic analog with a dinucleating ligand, LH,Ph (right), containing a 2-phenoxypyridyl group. Sol = solvent molecule.