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. Author manuscript; available in PMC: 2011 Jan 1.
Published in final edited form as: Org Lett. 2010 Jan 1;12(1):28–31. doi: 10.1021/ol9023908

Table 3.

Pd-catalyzed silylations with 1,2-diphenyltetramethyldisilane 2b.a

graphic file with name nihms162749t13.jpg

entry substrate productb yield(%)c
1 graphic file with name nihms162749t14.jpg graphic file with name nihms162749t15.jpg 91
2 graphic file with name nihms162749t16.jpg graphic file with name nihms162749t17.jpg 83
3 graphic file with name nihms162749t18.jpg graphic file with name nihms162749t19.jpg 93
4 graphic file with name nihms162749t20.jpg graphic file with name nihms162749t21.jpg 94
5 graphic file with name nihms162749t22.jpg graphic file with name nihms162749t23.jpg 91
6 graphic file with name nihms162749t24.jpg graphic file with name nihms162749t25.jpg 87
7 graphic file with name nihms162749t26.jpg graphic file with name nihms162749t27.jpg 95
8d graphic file with name nihms162749t28.jpg graphic file with name nihms162749t29.jpg 73
a

All reactions were carried out on 0.25 mmol scale.

b

l:b and E:Z ratio determined by GCMS and 1H NMR methods.

c

Isolated yield after column chromatography.

d

10 mol % PdCl2(DPEphos) used.