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. Author manuscript; available in PMC: 2010 May 1.
Published in final edited form as: Nat Chem. 2009 Nov 1;1(8):630–634. doi: 10.1038/nchem.410

Figure 4. Chirality of proline determines the absolute sense of asymmetric induction.

Figure 4

In previous work in the Miller group, the enantioselectivity of acylation reactions mediated by diastereomeric peptides was strongly dependent on whether the -turn of the peptide catalyst was nucleated by a D-Proline residue or an L-Proline residue.