Table 2.

Pd-Catalyzed Coupling of Aryl Nonaflates and Triflates with Secondary Ureas, Carbamates, and Sulfonamides.^a

entry	ArX	amide	product	yieldb
1				64%
2				53%
3				90%
4				88%
5				86%
6				87%
7				88%
8				83%
9				87%
10				77%

^aReaction conditions: ArONf/ArOTf (1 equiv), urea or carbamate (2.5 equiv), [(allyl)PdCl]₂ (1 mol%), JackiePhos (5 mol%), K₂CO₃ (2.0 equiv), 3 Å mol sieves (50 mg/ml), toluene (0.25 M), 110 °C, 17 h.

^bYields reported are an average of at least two runs determined to be >95% pure by elemental analysis or ¹H NMR.