Table 2.
Kinetic and Thermodynamic Parameters Derived from Dynamic 19F NMR Experiments
| B:S Ratio 20 ºC | 34%:66% |
| ΔG°20ºC | 0.39 kcal/mol |
| ΔH° | 4.04 kcal/mol |
| k30ºC | 300 s−1 |
| τ (1/k) | 3.33 ms |
| kC=2.22Δν | 921 s−1 |
| ΔG≠20ºC | 14.3 kcal/mol |
| ΔH≠ | 13.6 kcal/mol |
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