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Reaction mechanism of the oxygenase (PhaA) of HPAH from P. aeruginosa as deduced from the experimental analyses described in this paper.
Rate constants determined in this study are: k1 ≤ 2 × 106 M-1s-1; k2 = 3 × 105 M-1s-1; k3 ≤ 60 s-1; k4 = 28 s-1; k5 = 18 s-1; k6 = 2 s-1; k7 = 0.5 s-1.
