Table 5.
The open-circuit photovoltage (Voc), fill factor (FF), short-circuit photo-current density (Jsc), conversion efficiency (η) of the solar cells singly-sensitized and co-sensitized, and the spectral separation (S) and one-electron oxidation potential (Eox) of the sensitizers.
Principal and Co-sensitizers | Voc/V | FF | Jsc(Av)rJsc/mA·cm−2 | η(Av)rη/% | S | Eox/Vvs | |||||
---|---|---|---|---|---|---|---|---|---|---|---|
Phe a (a-type) a-type | 0.56 | 0.68 | 9.0 | 3.4 | 1.16 | ||||||
Mg-Phe a | 0.51 | 0.70 | 4.4 | 1.6 | 0.79 | ||||||
co-sensitization | 0.50 | 0.69 | 5.6 | (6.7) | 0.83 | 1.9 | (2.5) | 0.79 | 0.8 | 41 | |
Phe y | 0.49 | 0.70 | 5.2 | 1.8 | 1.19 | ||||||
co-sensitization b-type | 0.50 | 0.68 | 6.8 | (7.1) | 0.36 | 2.3 | (2.6) | 0.92 | 0.9 | 62 | |
Phe b | 0.53 | 0.70 | 4.6 | 1.7 | 1.24 | ||||||
co-sensitization c-type | 0.57 | 0.68 | 10.9 | (6.8) | 1.60 | 4.3 | (2.6) | 1.65 | 1.6 | 39 | |
Zn-Phe c1 | 0.62 | 0.63 | 10.4 | 4.0 | 1.16 | ||||||
co-sensitization | 0.60 | 0.69 | 11.9 | (9.7) | 1.23 | 5.0 | (3.7) | 1.35 | 1.3 | 80 | |
Mg-Phe c2 (Chl c2) | 0.58 | 0.66 | 9.9 | 3.8 | 1.06 | ||||||
co-sensitization | 0.60 | 0.64 | 14.0 | (9.5) | 1.47 | 5.4 | (3.6) | 1.50 | 1.5 | 95 |
The ratio of Jsc: ; The ratio of η: