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Outcome of trajectories versus the angle (see text) at which they leave the transition state. On this qualitative potential energy surface, the horizontal axis corresponds to motion along the 98-cm−1 vibrational mode and the orthogonal axis is motion along the transition vector. The arrows labeled a, b, c, and d refer to trajectories within a range of angles: a: <−26°; b: between −26° and 0°; c: between 0° and 26°; d: >26°.
