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. Author manuscript; available in PMC: 2010 Feb 10.
Published in final edited form as: J Am Chem Soc. 2007 Jun 2;129(25):7734. doi: 10.1021/ja0722473

Table 1.

Rate Constants for Reductive Eliminations from Pyridylpalladium Sulfonamidate 11 in the Presence of Different Lewis Acids

entry Lewis acid temp (°C) k (s−1 × 10−4) t1/2 (min)
1 BEt3 90 7.7 (0.8) 15
2 BEt3 70 ~170
3 BPh3 70 8.3 (0.2) 14
4 B(C6F5)3 40 6.8 (0.5) 17