TABLE 2.
Transformation of stereospecifically deuterated linoleic acids by nitrogen powder preparation of mycelia of M. oryzae Guy11
| [2H]18:2n-6 | Percent 2H | Percent Incorporation of 2H |
|
|---|---|---|---|
| 18:2n-6a | Oxygenated metabolites | ||
| % | % | ||
| (8R)-[2H]18:2n-6 | 64 | 57 | 59% (8R)-8-[2H]HODE |
| 59% (8R)-7,8-[2H]DiHODE | |||
| (7R)-[2H]18:2n-6 | 41 | 39 | 40% (7R)-8-[2H]HODE |
| 41% (7R)-7,8-[2H]DiHODE | |||
| (11S)-[2H]18:2n-6 | >95 | >95 | <1% (11S)-8,11-[2H]DiHODE |
a The deuterium content was determined in recovered 18:2n-6 from the experiments to correct for dilution of [2H]18:2n-6 by endogenous 18:2n-6 in the preparations (cf. Fig. 3A).