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. Author manuscript; available in PMC: 2011 Jan 1.
Published in final edited form as: Appl Magn Reson. 2010 Jan 1;37(1-4):39. doi: 10.1007/s00723-009-0042-2

Table 1.

g-Tensor principal values of quinone related radicals in RCs of Rb. sphaeroides and of model systems in nonprotic organic solvent

g value (±0.0001) Rb. sphaeroidesa Model systems


UQB(pH 7.0) RQB(pH 9.5) RQB(pH 4.5) UQ•−b RQ•−c
gx 2.0062 2.0057 2.0055 2.0070 2.0058
gy 2.0053 2.0048 2.0045 2.0054 2.0049
gz 2.0021 2.0020 2.0017

Values could not be measured accurately due to the overlapping with a small fraction of D•+ (see Fig. 3b, c)

a

Values obtained in this work using quintuple mutant RCs, in which the high-spin Fe2+ was replaced by diamagnetic Zn2+

b

Values corresponding to ubiquinone-3 (UQ-3) as taken from Ref. [19]

c

Values obtained in this work using rhodoquinone-3 (RQ-3)