Table 8.

Coupling of Functionalized Heteroaryl Chlorides with Primary Amines Catalyzed by Pd(OAc)₂ and CyPF-t-Bu (1:1).^a

Entry	Halide	R	Cat. (%)	Yield (%)b
1		Bn	0.5	73
2		secBu	0.5	96
3		Bn	0.5	59
4		isoBu	0.5	78
5		Octyl	0.5	53
6		Cyclohexyl	0.5	67
7		Octyl	0.5	79
8		Bn	0.5	55

^aReactions conducted with a 1:1 ratio of metal to ligand 1 mmol ArCl, 1.2 equiv amine and 1.4 equiv LiN(SiMe₃)₂ in 1 mL DME.

^bIsolated yields.