Table 1.

Parameters of pump-probe dynamics fit for different temperatures and samples.

Sample	Temp. (K)	Population dynamics						Anisotropy
		Rise		Decay
		A1	τ1 (ps)	A2	τ2 (ps)	A3	τ3 (ps)	τα (ps)
TFA-C12	281	1	0.47±0.02	0.75±0.06	0.58±0.07	0.25±0.06	2.8±0.5	⋯
	293	1	0.47±0.02	0.74±0.04	0.54±0.06	0.26±0.04	3.2±0.4	4.3±0.5
	323	1	0.36±0.02	0.72±0.04	0.51±0.06	0.28±0.02	2.7±0.3	⋯
TFA-C13	293	1	0.36±0.02	0.89±0.02	0.44±0.02	0.11±0.02	3.6±0.5	4.3±0.5