TABLE 2.
Conversion of cis-Alkenyl Pinacolboronates to the Corresponding Trifluoroboratesa

| entry | R | product | % isolated yield |
|---|---|---|---|
| 1 | ![]() |
![]() |
83 |
| 2 | ![]() |
![]() |
83 |
| 3 | ![]() |
![]() |
82 |
| 4 | ![]() |
![]() |
78 |
| 5 | ![]() |
![]() |
78 |
| 6 | ![]() |
![]() |
72 |
| 7 | ![]() |
![]() |
62 |
All reactions were carried out using 2 mmol of b in MeOH (0.5 M) and 10 mmol of KHF2 (4.5 M).













