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. Author manuscript; available in PMC: 2011 Mar 5.
Published in final edited form as: J Org Chem. 2010 Mar 5;75(5):1795–1798. doi: 10.1021/jo902697g

Table 5.

Enantioselective Carbonyl tert-Prenylation Furan Methanols via Iridium Catalyzed Transfer Hydrogenation.a

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Entry Furan Methanol Product Isolated Yield ee (%)
1 R = H, 1a 5a 82% 87 (R)
2 R = Me, 1b 5b 84% 84 (R)
3 R=Ar, 1c 5c 91% 85 (R)
a

As described for Table 1.