Table I.
Vibrational Frequencies (in cm−1) and Assignments of Peaks Found in the Spectra of Cells
3300 | Amide A (N–H stretching mode, peptide linkage) |
2950 | CH3 antisymmetric stretching mode |
2920 | CH2 antisymmetric stretching mode |
2880 | CH3 symmetric stretching mode |
2850 | CH2 symmetric stretching mode |
1735 | >C=O stretching mode, ester linkage |
1690–1620 | Amide I (>C=O stretching mode, peptide linkage) |
1570–1530 | Amide II (C–N stretching mode, peptide linkage) |
1468–1455 | CH3/CH2 antisymmetric bending mode |
1397 | –COO– symmetric stretching |
1379 | CH3 symmetric bending mode |
1340–1240 | Amide III (coupled N–H/C–H deformations) |
1237 | O–P=O antisymmetric stretching mode |
1150 | C–O stretching, C–O–H bending modes (carbohydrates, mucin) |
1083 | O–P=O symmetric stretching mode |
1063 | –CO–O–C symmetric stretching mode |
1050 | C–O stretching mode (carbohydrates, mucin) |
1004 | Phenylalanine ring breathing mode |
968 | C–O–P phosphodiester residue (DNA) |