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. Author manuscript; available in PMC: 2010 Mar 2.

Published in final edited form as: Bioconjug Chem. 2008 Mar 14;19(4):958–965. doi: 10.1021/bc700413r

Table 3.

Yield of the M[16aneS₄-diol]X (M = Rh(III) or Ir(III) and X = *I or ²¹¹At) Complexes Synthesis vs pH of Solution

	yield ± SD [%]
pH	Rh[16aneS₄- diol]*I	Ir[16aneS₄- diol]*I	Rh[16aneS₄- diol]²¹¹At	Ir[16aneS₄- diol]²¹¹At
2.0	80.6 ± 3.2	74.7 ± 2.4	72.2 ± 8.1	68.9 ± 6.1
3.0	83.3 ± 2.9	76.5 ± 1.7	75.3 ± 4.5	74.8 ± 3.2
4.0	84.2 ± 4.3	80.2 ± 2.9	80.4 ± 4.2	75.1 ± 6.4
5.0	55.1 ± 9.4	65.7 ± 3.1	68.1 ± 3.6	69.0 ± 6.0
6.0	32.6 ± 8.2	62.4 ± 2.5	43.3 ± 3.4	58.4 ± 5.3
7.5	14.0 ± 7.7	27.3 ± 6.7	24.7 ± 5.2	35.0 ± 1.7
8.5	4.5 ± 0.4	-	12.4 ± 6.7	-