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. Author manuscript; available in PMC: 2011 Mar 10.
Published in final edited form as: J Am Chem Soc. 2010 Mar 10;132(9):2983–2990. doi: 10.1021/ja908395r

Scheme 3.

Scheme 3

Proposed mechanism for riboflavin synthase via hydride transfer. Tautomerization reactions (tautomer pairs 2a/2b and 14a/14b, respectively) are indicated by double arrows.