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. 1997 Dec 9;94(25):13554–13558. doi: 10.1073/pnas.94.25.13554

Table 1.

Camphor hydroxylation for several bioelectrochemical reactor conditions

Reactor solution composition* Oxygen condition Product turnover rate, nmol of 5-exo-camphor/min per nmol of CYP101
41 μM Pdx Ar purge 0
12.8 μM CYP101 Ar purge 0
41 μM Pdx + 0.41 μM CYP101 Air saturated 0.9
55 μM Pdx + 0.18 μM CYP101 Ar purge 4.2
108 μM Pdx + 0.23 μM CYP101 Ar purge 6.4
1030 μM Pdx + 0.13 μM CYP101 Ar purge 34
1030 μM Pdx + 0.13 μM CYP101 Ar purge 36
*

Standard experimental electrolysis reaction conditions: buffer was 50 mM Tris⋅HCl, 0.18 M KCl. 16 mM MgCl2; 800 μM initial camphor concentration; Ewe = −0.7 V on the tin oxide working electrode; temperature was 21–22°C. 

Standard condition except initial camphor concentration was 2 mM. 

Standard condition except initial camphor concentration was 2 mM and temperature was 37°C.