. Author manuscript; available in PMC: 2011 Mar 3.

Published in final edited form as: J Am Chem Soc. 2010 Mar 3;132(8):2811–2820. doi: 10.1021/ja910005b

Table 2.

Fitting parameters of NO rebinding kinetics in ferric NP4 extracted using the kinetic model developed in section 2. All rates are in units of 10⁹ s⁻¹. The equilibrium off rate, $k_{off} = k_{AB}^{o} P_{o} (1 - I_{g}^{o})$ . The amplitude for geminate recombination in the closed state is taken to be unity.

pH	P_c	k_g^c	k_BA^c	P_o	k_g^o	I_g^o	k_BA^o	k_out^o	k_off/k_AB^o
5.0	0.96	64	64	0.04	7.4	0.90	6.7	0.74	0.004
8.0	0.79	40	40	0.21	6.1	0.67	4.0	2.0	0.069