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. Author manuscript; available in PMC: 2011 Mar 19.
Published in final edited form as: Org Lett. 2010 Mar 19;12(6):1200–1203. doi: 10.1021/ol902970z

Table 4.

Iron Catalysisa

graphic file with name nihms183622t19.jpg

entry Ar-H, base product yield,
%
1 Thiazole, base 1 +
base 3 (4.7/1)
graphic file with name nihms183622t20.jpg 59
2 4,5-Dimethylthiazole,
base 1
graphic file with name nihms183622t21.jpg 68
3 N-Methylbenzimid-
azole, base 1
graphic file with name nihms183622t22.jpg 77
4 Tetrafluoropyridine,
Base 3
graphic file with name nihms183622t23.jpg 54
5 Tetrafluoroanisole,
base 1 + base 3 (0.9/1)
graphic file with name nihms183622t24.jpg 78
6 Ethyl 2,4-difluoro-
benzoate, base 1 +
base 3 (4.6/1)
graphic file with name nihms183622t25.jpg 70
a

Substrate (1 equiv), base (1.1–1.3 equiv). Yields are isolated yields. See Supporting Information for details.