. Author manuscript; available in PMC: 2010 Apr 7.

Published in final edited form as: Macromolecules. 2009 Feb 10;42(3):599–605. doi: 10.1021/ma801693q

Table 6.

Effect of Increasing [M]₀/1 for Polymerization of 6a and 6b^a

entry	monomer	[M]₀/1	M_n (×10³g/mol)	M_n (theo) (×10³ g/mol)	PDI	% yield
20	6a	200	41	43	1.06	68
21	6a	400	110	87	1.03	82
22	6a	600	163	130	1.03	88
23	6a	800	200	173	1.02	84
24	6a	1000	266	216	1.02	93
25	6b	200	55	48	1.02	48
26	6b	400	117	96	1.02	93
27	6b	600	170	144	1.02	85
28	6b	800	249	192	1.02	85
29	6b	1000	321	240	1.02	93

Polymerization conducted with PPh₃/1 = 60, [M]₀ = 0.25 M, at 23°C for 5 min.