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. 2010 Mar 22;110(4):2049–2080. doi: 10.1021/cr900227t

Table 1. Chemical and Physical Data of d-Glucose.

chemical name (IUPAC) 6-(hydroxymethyl)oxane-2,3,4,5-tetrol
synonym dextrose
varieties α-d-glucose; β-d-glucose
appearance colorless crystals or white crystalline powder
abbreviation Glc
chemical formula C6H12O6
molecular mass 180.16 g/mol
melting point α-d-glucose: 146 °C
β-d-glucose: 150 °C
α-d-glucose·monohydrate: 86 °C
specific rotation, (α)20D (water) α-d-glucose: +112.2° (c = 4)
β-d-glucose: +17.5° (c = 4)
α-d-glucose·monohydrate: +102°
density 1.54 g/cm3
solubility (in water) 0.909 g/mL (25 °C)
CAS number 50-99-7
PubChem 5793
reactivity of hydroxyl groups 1 ≫ 6 > 2,3 > 4
NMR data (D2O)
α-d-glucopyranose
β-d-glucopyranose
1H δ (ppm) J (Hz) 13C δ (ppm) 1H δ (ppm) J (Hz) 13C δ (ppm)
5.22 3.5 93.6, 92.9d 4.63 7.9 97.4, 96.7d
In α-glucan chains
reducing end
−(1,4)-α-d-Glc −(1,6)-α-d-Glc
5.22b 3.7b 92.9a 5.00e   92.0a
internal
−α-d-Glc-α-d-Glc-(1,4)-α-d-Glc− −α-d-Glc-α-d-Glc-(1,6)-α-d-Glc−
5.31−5.40b 3.7b 100.6a,100.2−100.9b 4.96b 3.7b 98.6a, 99.3b
nonreducing end
α-d-Glc-(1,4)− α-d-Glc-(1,6)−
5.35c 3.8c 100.8a 4.89e   98.5a
a

Ref (306).

b

Ref (107).

c

Ref (200).

d

Ref (307).

e

Ref (269).