Table 9. Boiling Temperatures, Tb, Water Content W, Glass Transition Temperature, Tg, and viscosity, η, of Various Stages of Syrupsa.
stage | Tb/°C | W (% w/w) | Tg/°C | η(25 °C)/Pa s |
---|---|---|---|---|
thread | 110−111 | 20 | −50 | 101 |
soft ball | 112−115 | 15 | −30 | 102 |
firm ball | 118−120 | 13 | −25 | 103 |
hard ball | 121−130 | 8 | 0 | 106 |
soft crack | 132−143 | 5 | 20 | 1010 |
hard crack | 146−154 | 1 | 50 | 1019 |
Although not quantitatively accurately, these data give an impression of the ranges of material properties embraced by mixtures of the two components, sugar and water. Water contents were estimated from McGee,(233) Chapter 12. Glass transition temperatures were estimated using the Gordon−Taylor equation from glass transition temperatures of water and dry sucrose. The viscosity was estimated using the WLF equation and the set of universal constants.