C
D
|
drag coefficient (dimensionless) |
D
TCE−water
|
diffusion coefficient (m2/s) |
Fe |
total quantity of all iron species (mmol) |
(H2O2)0
|
initial total quantity of hydrogen peroxide (mmol) |
[H2O2] |
hydrogen peroxide concentration (mmol/L) |
[H2O2]0
|
initial hydrogen peroxide concentration (mmol/L) |
k
c
|
mass transfer coefficient (m/s) |
k′TCE
|
fitted first-order rate constant for constant [OH·] model
(s−1) |
k″TCE
|
observed rate constant for varying [OH·] model
(dimensionless) |
M
TCE
|
molecular weight of TCE (g/mol) |
n
|
number of TCE droplets (dimensionless) |
[OH·] |
hydroxyl radical concentration (mmol/L) |
R
|
droplet radius (m) |
Re |
Reynolds number (dimensionless) |
S
|
surface area of single droplet (m2) |
Sc
|
Schmidt number (dimensionless) |
Sh
|
Sherwood number (dimensionless) |
TCE0
|
initial total quantity of TCE (mmol) |
[TCE]aq
|
aqueous-phase TCE concentration (mmol/L) |
[TCE]aq,0
|
initial aqueous-phase TCE concentration (mmol/L) |
[TCE]sat
|
TCE saturation concentration (mmol/L) |
U
|
velocity of droplet relative to surrounding fluid (m/s) |
V
|
reactor volume (L) |
W
r
|
mass flux in radial direction (mmol s−1
m−2) |
α |
proportionality constant relating [OH·] and
d[H2O2]/dt [Equations
(30, 31)] (s) |
δ |
droplet boundary layer thickness (m) |
ν |
kinematic viscosity of water (m2/s) |
ρTCE
|
density of TCE (g/m3) |