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. Author manuscript; available in PMC: 2010 Apr 25.
Published in final edited form as: Arch Biochem Biophys. 2006 Apr 15;448(1-2):73–82. doi: 10.1016/j.abb.2005.10.028

Scheme 5.

Scheme 5

Cyclization of carbocations along the (Z,E)-farnesyl cation pathway. Selected atoms are labeled to illustrate the stereo-chemical rationalization for isoprezizaene (8) biosynthesis.