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. Author manuscript; available in PMC: 2010 Oct 22.
Published in final edited form as: J Phys Chem B. 2009 Oct 22;113(42):14026–14034. doi: 10.1021/jp902291n

Figure 5.

Figure 5

The proportionality coefficient A in the relationship keff=Ak0δ varies strongly as a function of the length scale of quenching and polymer length. Much of this variation is captured by the approximate formula A = a(1/τr)1−δ, where τr is the polymer's inherent relaxation time (eq 23), a = 0.5, and the scaling exponent δ is estimated using the universal curve δ(g) of Figure 4b. The predictions of this formula are plotted as solid lines.