Table 2.

Fluorescence parameters at 298 K^a,^b

Compound	Excited State	λmax (nm)	τ (ns)	Φ	E00 (eV)
1	1ZnP*-Cu+-C60	603	0.5	1.0 × 10−2	2.09
	1ZnP-*Cu+-C60	762	---	8.6 × 10−5	1.62
2	3MLCT	765	---	4.8 × 10−3	1.62
3	1ZnP*-Cu+	603	0.5	1.0 × 10−2	2.09
	ZnP-*Cu+	762	---	5.3 × 10−4	1.62
4	*Cu+-C60	765	---	2.5 × 10−4	1.62
	Cu+-1C60*	710	0.1	2.3 × 10−5	1.75
17	1C60*	710	1.4	6.0 × 10−4	1.75
	3C60*	790	2.0 × 104	0.98	1.50c
18	1ZnP*	600	2.3	4.0 × 10−2	2.09
	3ZnP*	802	4.5 × 104	0.88	1.55c

^aAll samples in oxygen free dichloromethane (DCM). Optical densities (ODs) were in the range of 0.12 (C₆₀, 355 nm), 0.14 ([Cu(phen)2]⁺ complex, 320 nm) and 0.4 (ZnP, 420 nm).

^bλ_max = emission maximum; τ = fluorescence lifetime; Φ = fluorescence quantum yield; E00 = the energy of the corresponding excited state relative to the ground state, calculated from the emission maxima (λ_max).

^cFrom reference ^7d.