Table 2.
Polymer | Structure | NMR (ppm) | Mw (g/mol) | Tg (°C) | XPS (%) | ||
---|---|---|---|---|---|---|---|
31P | 1H | ||||||
PNEA | −1.10 | 4.4 (1H) | 408,000 | −3.0 | C | 56.1 | |
4.1 (2H) | O | 26.2 | |||||
1.6 (3H) | N | 12.4 | |||||
1.3 (3H) | P | 5.3 | |||||
PNEA50mPh50 | −5.07 | 6.8 (4H ) | 4,608,000 | −6.0 | C | 63.2 | |
3.9 (3H) | O | 22.3 | |||||
2.2 (3H) | N | 9.2 | |||||
1.8 (3H) | P | 5.2 | |||||
PNEA50PhPh50 | 1.78 | 7.4 (9H) | 4,350,000 | 35.2 | C | 67.0 | |
−5.12 | 4.4 (1H) | O | 26.8 | ||||
−14.58 | 4.1 (2H) | N | 4.1 | ||||
1.4 (3H) 1.2 (3H) |
P | 2.0 | |||||
PLAGA | – | – | 1,35,000 | 65.0 | – |