Table 14.

Resolution of 3-substituted cyclic allylic alcohols.

entry	alcohol, major enantiomer	conditions[a]	time	conv.[b]	alcohol ee[c]	s
1		A	4 h	53%	99%	83
2		B	1 h	53%	98%	63
3		D	6 h	55%	94%	26
4		A	4 h	56%	99%	50
5		B	1 h	56%	99%	51
6		C	9 h	51%	95%	83
7		A	8 h	73%	98%	8.6
8		B	1 h	61%	85%	9.0
9		C	10 h	78%	99%	7.5
10	R = Me R = Bn	B	8 h	65%	99%	15
11		C	27 h	58%	94%	19
12		D	43 h	64%	97%	13
13		C	72 h	61%	91%	11

^[a–c]See Table 10 footnotes.