Table 2.

Products from [(TPFPP)Cr^III]⁺ (1) + ligands and their behavior upon CID.

synthesisa	L	Product	CID reaction	Eappb
Sc	PhIO	2	-	-
S	γ-picoline-O	+L	1-L → 2 + γ-picoline (90%)	0.48
			1-L → 1 + γ-picoline-O (10%)	0.58
S,G	γ-picoline	+L	1-L → 1 + γ-picoline	0.55
S	py-O	+L	1-L → 2 + py (75%)	0.41
			1-L → 1 + py-O (25%)	0.38
S,G	py	+L	1-L → 1 + py	0.56
G	NO2	2d	–c	–
G	C2H4O	+L, +2L	1-L → 1 + L	–e
			1-L2 → 1-L + L	–e
S	DMSO	+L	1-L → 1 + L	0.43
G	Me2S	+L, +2L	1-L → 1 + L	–e
			1-L2 → 1-L + L	–e
S,G	TEMPO	+L	1-L → TEMPO+ + [(TPFPP)CrII]	–e
S	OPPh3	+L, + 2L	1-L → 1 + L	0.56
S,G	OP(OMe)3	+L, + 2L	1-L → 1 + L	0.58
			1-L2 → 1-L + L
S,G	P(OMe)3	+ L	1-L → 1 + L	0.31

^aS = prepared in solution from 5 μM 1-Cl + 5 μM LO in MeOH, followed by electrospray; G = formed in the gas phase from 1 + L.

^bPhenomenological appearance energies in kcal mol⁻¹.

^cThe so-formed ion 2 is stable towards CID in the energy range explored.

^dEfficiency 22%.

^eNot available.