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Halogenated eicosanoids (C18 oxylipins derived from stearidonic acid), isolated from the Laminariale Egregia menziesii [41]. (a) Egregiachloride A and B from stearidonic acic catalysis by 13LOX, cyclopentyl cyclization and subsequent carbocation attack at C16 by chlorine anion. (b) Egregiachloride C, similarly synthesized from eicosapentaenoic acid.
