Table 1.
Spectroscopic Properties of Selected ‘Non-Covalent’ Probesa
# | name | solvent | λmax (ε) | λem | Φ | τ |
---|---|---|---|---|---|---|
4.1 | DPHb | EtOH | - | - | 0.24 | 2.2 |
hexane | 352, 370 | 430 | 0.64 | 15.7 | ||
4.2 | M-9-A | MeOH | 361 (7.1) | 461 | 0.071 | - |
hexane | - | 447 | - | 12.1 | ||
4.3 | Perylenec | EtOH | 252, 408 (63.1), 434 | - | - | - |
dodecane | - | - | 0.89 | 4.9 | ||
4.4 | Pyrenec,d | EtOH | 241 (79.4), 272, 334 | 376 | 0.65 | 410 |
4.5 | ANSe | Water | 340 | 555 | 0.003 | 0.42 |
dioxane | - | 472 | 0.57 | 11.8 | ||
4.7 | DCVJ | MeOH | 455 (62) | - | 0.0022 | - |
glycerol | 469 | 508 | - | - | ||
4.8 | FCVJ | ethylene glycol | 483 | 503 | - | - |
λ, ε, and τ are given in nm, 103 M−1cm−1, and ns respectively
ε is given only for the most intense λabs.170
λem, Φfl and τ are from Hermetter.142
λabs is extracted from a graph, λem is highly solvent polarity sensitive, several values for λem and τ have been reported, some of which are contradicting.154